Corrosion by Hot CO<sub>2</sub> Gases

نویسندگان

چکیده

Heat-resisting alloys are designed to survive high-temperature oxidation by forming a slow-growing scale, usually Cr 2 O 3 , which acts as barrier between the metal and its environment. However, that succeed in this way when exposed hot oxygen or air fail do so CO gas. Instead, they exhibit rapid “breakaway” corrosion, developing oxides of alloy base iron and/or nickel. The growth these non-protective scales is accompanied internal carburization underlying alloy. Carbon passes through oxide, dissolves alloy, precipitates chromium carbide. Removal from matrix makes incapable reforming chromia, recovery breakaway becomes impossible.

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ژورنال

عنوان ژورنال: The Electrochemical Society interface

سال: 2021

ISSN: ['1064-8208', '1944-8783']

DOI: https://doi.org/10.1149/2.f08212if